Effects of annealing conditions on ferroelectric nanomesa self-assembly

نویسندگان

  • Stephen Ducharme
  • Mengjun Bai
  • Matt Poulsen
چکیده

We report the results of studies of the effects of annealing conditions on the morphology of ferroelectric nanomesas. The nanomesa patterns were fabricated by self-assembly from continuous ultra-thin Langmuir–Blodgett fi lms of copolymers of vinylidene fl uoride and trifl uoroethylene. Annealing in the paraelectric phase induced surface reorganization into disc-shaped ferroelectric nanomesas approximately 9 nm thick and 100 nm in diameter. Several factors affect the nanomesa dimensions, such as polymer composition, substrate material, deposition conditions, and annealing temperature. The height and diameter of the nanomesas both increase with increasing annealing temperature. Annealing studies in the ferroelectric–paraelectric coexistence region show that only the paraelectric phase is mobile. From this we conclude that the paraelectric phase supports a kind of plastic crystalline fl ow connected with dynamic disorder of the poly-

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تاریخ انتشار 2017